I really wouldn't rely on RAID as your only form of protection. Frankly, from my experience of hardware RAID, it fails much more than you would expect it to, and data recovery from a RAID'd drive is much more difficult than a simple drive. Software RAID is often worse!
Check out another thread I am running at the moment on the subject of metadata for media. Under 0710b3 and up it seems that the metadata is much more transportable and less reliant on the database, which could address your concerns. Unless you are concerned about all the other stuff in the database, like your device configuration.
In which case, I would say look for a MySQL backup tool and back the DB up yourself, to your RAID drive. I am hoping also to then back up my media drives incrementally to DVDs ( which in your case would include your DB) - yet to track down a reasonable backup tool to do it...