Rule #1 - Be Patient - Rule #2 - Don't ask when, if you don't contribute - Rule #3 - You have coding skills - LinuxMCE's small brother is available: http://www.agocontrol.com
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One comment I would make is the motherboard you have chosen includes the new Intel GMA3100 Graphics chip and since you have not specified a separate nVidia Card I assume your plan is to use the onboard video. We have not tested the GMA3100 with the latest Intel drivers so I cannot say for sure that it will configure smoothly with the current builds of LinuxMCE-0710... but I would expect it to. If that proves to be correct then you will get UI2 with Overlay ok but you may find that the pss will lock up if the animated images option is left at its default setting. If you set the pss to use 'static' images then that problem goes away however.
All the best