I am not a linux guru either but I saw this on the wiki.
Short to say create a directory on the windows share.
Make a network mount to that share in the directory structure explained below
If you want to add more storage you can map drives under those directories. For example, if you have another 2TB drive array that you want to use for both public music and your private movies, create 2 directories on that array, let's say: public_music and john_movies. Using a network mount, or a symlinc to a network mount, create a folder such as /home/public/data/music/my_2TB_nas that maps to public_music and /home/user_xxxx/data/movies/my_2TB_nas that maps to john_movies.http://wiki.linuxmce.com/index.php/How_are_media_files_organized%3F