Also note that the dhcp server will be running in the VM in LMCE and as soon as you stop it (for backups or upgrades) you will have to find a nice way to still be able to connect to proxmox.
Rule #1 - Be Patient - Rule #2 - Don't ask when, if you don't contribute - Rule #3 - You have coding skills - LinuxMCE's small brother is available: http://www.agocontrol.com
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I am always laughing when I see people wanting to control the temperature in a room. This must be something from a different country, or mind set.
In my mindset, I set the temperature for a room once, I might modify it empirical over time, but never ever do I change the temperature in a room daily or on a time schedule. Way more expensive to reheat a room, than to keep a room at a specific temperature. Maybe other countries/homes are different, but that is the scientific consensus in Germany.